Cumulative impacts on water quality functions of wetlands

The total effect of cumulative impacts on the water quality functions of wetlands cannot be predicted from the sum of the effects each individual impact would have by itself. The wetland is not a simple filter; it embodies chemical, physical, and biotic processes that can detain, transform, release, or produce a wide variety of substances. Because wetland water quality functions result from the operation of many individual, distinct, and quite dissimilar mechanisms, it is necessary to consider the nature of each individual process.Sound knowledge of the various wetland processes is needed to make guided judgements about the probable effects of a given suite of impacts. Consideration of these processes suggests that many common wetland alterations probably do entail cumulative impact. In addition to traditional assessment methods, the wetland manager may need to obtain appropriate field measurements of water quality-related parameters at specific sites; such data can aid in predicting the effects of cumulative impact or assessing the results of past wetland management.     

Mineralization of CCl4 by the UVC-photolysis of hydrogen peroxide in the presence of methanol

A method for a photochemically induced mineralization of CCl4 is described in which use is made of reductive radicals. The UVC-photolysis (254 nm) of H2O2 added to aqueous solutions of CCl4 is leading to the homolysis of the oxidant yielding hydroxyl radicals (HO) that subsequently react with added methanol to generate hydroxymethyl radicals (CH2OH). The latter radicals initiate mineralization of CCl4 by reductive C-Cl bond splitting. CHCl3, C2Cl4 and C2Cl6 were found as reaction intermediates, but are quantitatively depleted in a parallel oxidative reaction manifold leading to mineralization. Carbon dioxide radical anion, CO2(-), an intermediate in the mineralization pathway of methanol, is also shown to initiate the mineralization of CCl4 by reductive dechlorination. A reaction mechanism is proposed and validated with computer simulations of all the experimental results.